硬脂酸柱撑类水滑石的制备及应用

采用离子交换法制备了硬脂酸柱撑类水滑石,并用红外光谱分析对其进行了表征.通过HAAKE流变仪、颜色测定仪研究了硬脂酸柱撑类水滑石与钙锌热稳定剂并用时的热稳定性,重点考察了水滑石的结构对PVC稳定性能的影响.结果表明硬脂酸柱撑类水滑石与钙皂/锌皂复配显著改善了PVC热老化过程中的初期着色性.     

Synthesis, characterization of bimetallic Sn-Zn-MCM41 and its catalytic performance in the hydroxylation of phenol

A series of Sn-Zn modified-MCM41 has been synthesized by direct hydrothermal method and characterized using ICP, XRD, TG/DTA, FT-IR, HRTEM and N_2-adsorption techniques. Catalytic performances of the obtained materials were evaluated in the hydroxylation of phenol with H₂O₂. Results indicated that all the samples exhibited typical hexagonal arrangement of mesoporous structure with high surface area and the heteroatoms were probably incorporated into the framework of MCM41. Catalytic tests revealed that the bimetallic incorporated materials were effective catalysts in the hydroxylation of phenol. The conversion of phenol could be reach to 56.8% for the catalysts with Sn: Zn: Si = 2.69: 4.57: 100 (molar ratio) under the optimized reaction conditions. Moreover, the materials containing Sn and Zn exhibited higher catalytic activity than monometallic Sn and Zn modified MCM41.     

气相法改性纳米二氧化硅表面

采用硅烷偶联剂A-151处理的纳米二氧化硅粒子，具有良好的疏水性，并且反应副产物没有腐蚀性，有利于保护设备和环境保护。分别用表面羟基数、亲油化度等性能来表征改性纳米二氧化硅的效果。红外光谱分析表明A-151确实已经和纳米二氧化硅表明的羟基发生了化学反应，通过透射电镜研究发现改性后纳米二氧化硅在乙醇中达到纳米级的分散。     

A new core–shell type fluorinated acrylic and siliconated polyurethane hybrid emulsion

A novel core–shell type fluorinated acrylic and siliconated polyurethane (FSiPUA) hybrid emulsion was prepared by seeded emulsion polymerization using siliconated polyurethane (SiPU) as a seed and forming the structure with SiPU as a shell and the copolymer of butyl acrylate (BA) with 2,2,2-trifluoroethylmethacrylate (TFEMA) as a core. SiPU was synthesized using isophorone diisocyanate (IPDI), polytetramethylene ether glycol (PTMG), polypropylene glycol (PPG), dihydroxybutyl-terminated polydimethylsiloxane (PDMS), dimethylol propionic acid (DMPA), 1,6-hexanediol (HDO) and triethylamine (TEA). The contents of siloxane and fluorine were determined according to the feed ratio. Fourier transform infrared spectroscopy (FTIR) was used to identify the chain structure of SiPU and FSiPUA. Investigation of transmission electron microscopy (TEM) confirmed the core–shell structure of FSiPUA emulsion and gave the particle size at about 50 nm. The measurement results of water contact angles and the solvent absorptions in water and n-octane for cured films showed that the water and the oil repellency for FSiPUA had been improved significantly with a suitable content of fluorine and siloxane.     

振动力场对聚丙烯/硅灰石复合材料性能的影响

采用三螺杆动态混炼挤出机通过熔融共混制备了聚丙烯(PP)/硅灰石复合材料,研究了振动工艺参数对材料力学性能及微观形态结构的影响。结果表明,PP/硅灰石复合材料的力学性能对振动参数的响应并不是单调增加,而是存在一个最佳的响应范围。在这一范围内,其综合力学性能得到极大提高。     

A_1-A_2-O-M工艺处理焦化废水的实验研究

采用厌氧-缺氧-好氧-复合(A1-A2-O-M)工艺处理焦化废水,考察了外加碳源和碱源对焦化废水COD和NH4+-N脱除效果的影响。试验结果表明:外加甲醇和碳酸氢钠对焦化废水的硝化和反硝化效果影响很小;不外加碳源和碱源时,焦化废水经处理后出水的COD和NH4+-N平均质量浓度分别为125.0mg/L和1.12mg/L,分别达到《污水综合排放标准》(GB8978-1996)中的二级标准和一级标准。     

氯乙烯生产控制系统的改造

介绍了横河公司的分布式控制系统CS3000在氯乙烯生产过程中的应用情况,阐述了该系统的工艺流程、硬件配置、软件配置和主要功能。     

基于FPGA实现AES的侧信道碰撞攻击

为了解决攻击点在能量迹中具体位置的识别问题,在对侧信道碰撞攻击技术研究的基础上,提出了通过计算能量迹中每个采样点的方差来识别攻击点的方差检查技术。并利用基于相关系数的碰撞检测方法,对一种AES的FPGA实现实施了攻击。实验结果表明,方差检查技术可以有效地识别攻击点在能量迹中的具体位置。     

基于硬件Kalman滤波器的航拍云台姿态获取

航拍云台姿态获取是航空摄影中相机姿态校正的基本依据,介绍了一种基于硬件Kalman滤波器的航拍云台姿态获取的实现方法。设计中采用MPU6050作为系统的姿态传感器,它提供三轴角速度和三轴加速度数据。根据系统特征建立Kalman滤波方程对这些数据进行数据融合处理,Kalman滤波过程中的加减乘除浮点数运算由FPGA实现,外部数据的采集和时序的控制也由FPGA完成。经过对实际数据的处理实验,得出该硬件模块可以获得较为准确的航拍云台姿态,输出结果误差在-1.5°~1.5°范围内。     

基于最佳竞争窗口的IEEE802.11DCF接入协议改进及性能分析

针对DCF协议的初始竞争窗口不能随着节点数变化选择其最佳值的不足,提出一个具有两级退避的接入协议(OCW-DCF),并用Markov模型分析了协议性能,确定其最佳竞争窗口值。仿真结果表明,OCW-DCF协议能有效减小信道接入延时,且采用基本接入模式的总体性能比RTS/CTS接入模式的好。